Credit: Splash News Online

And she's off.

After her PDA-packed Super Bowl appearance with Brad Pitt, Angelina Jolie jetted off to the Dominican Republic Monday to visit hospitalized Haitian earthquake survivors and meet with Dominican President Leonel Fernandez.

On Tuesday, the 34-year-old UN goodwill ambassador -- who is suing a British tabloid for claming that she plans to split from Brad Pitt -- is expected to travel to Haiti, UNHCR spokesman Andrej Mahecic said Tuesday. He is keeping her itinerary secret for security purposes.

Last month, Jolie -- who has visited everywhere from Iraq to Thailand to Pakistan -- announced that she and beau Pitt, 46, are donating $1 million to the emergency medical operation in Haiti.

In a statement, she said: "It is incredibly horrible to see a catastrophe of this size hit a people who have been suffering from extreme poverty, violence and unrest for so many decades."