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PICTURE: Newlyweds Justin Timberlake, Jessica Biel Hold Hands on Skyfall Movie Date

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Newlyweds Justin Timberlake and Jessica Biel catch the movie 'Skyfall' in NYC on November 11, 2012.

On Sunday, Mr. and Mrs.  Justin Timberlake bonded over Bond — James Bond.

Justin Timberlake and  Jessica Biel were photographed holding hands in NYC on Sunday, Nov. 11; the recently married couple headed into an early matinee of Skyfall, the latest James Bond flick starring Daniel Craig (which had the biggest opening ever for any film in the franchise).

Related: PHOTOS: Justin and Jess through the years

The evening before, Timberlake, 31, and Biel, 30 — they married in southern Italy Oct. 19 and honeymooned in Tanzania — were spotted catching Anne Hathaway and Rihanna during a Saturday Night Live taping.

Related: PHOTOS: Jessica's hot body evolution

 But it hasn't been all play and no work for the husband and wife during their stay in the Big Apple. During the day on Saturday, they were among the volunteers handing out much-needed supplies to victims of Hurricane Sandy in Rockaway, Queens.

Related: PHOTOS: Justin's style evolution

 "Taking in the devastation caused by Hurricane Sandy . . . my thoughts and prayers go out to everyone that was affected," singer-actor Timberlake tweeted Nov. 1. Biel also tweeted, "Sending my prayers and love to New York City and to everyone affected by Hurricane Sandy." See more photos of the newlyweds in the Big Apple.

Click here for more ways on how you can help Hurricane Sandy victims. 

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