Team Jen or Angelina? The 2005 triangle bombshell between Jennifer Aniston, Brad Pitt and Angelina Jolie continues to make headlines. Cheating rumors swirled in 2005 while Pitt and Jolie starred together in the film Mr. & Mrs. Smith. That same year, Pitt and Aniston divorced after five years of marriage, and Pitt and Jolie were soon spotted during a romantic getaway that April. "Brangelina" became engaged in 2012 and share six kids together.