From Mr. and Mrs. Smith to Mr. and Mrs. Pitt! Brad Pitt and Angelina Jolie have had quite the journey from costars, to parents, to spouses. The A-list couple had a scandalous start to their romance when they met on the set of Mr. & Mrs. Smith, while Pitt was still married to Jennifer Aniston. But the couple, who are parents to six kids, has built a long-lasting relationship. Click through to see their romantic history.
The couple shared the first photos of twins Knox and Vivienne with Hello! for a reported $14 million — the most expensive celebrity pictures ever taken. "We felt we could handle more children, and we have a very happy, very full home," Jolie has said of her large brood.