From Mr. and Mrs. Smith to Mr. and Mrs. Pitt! Brad Pitt and Angelina Jolie have had quite the journey from costars, to parents, to spouses. The A-list couple had a scandalous start to their romance when they met on the set of Mr. & Mrs. Smith, while Pitt was still married to Jennifer Aniston. But the couple, who are parents to six kids, has built a long-lasting relationship. Click through to see their romantic history.
Considered to be the best-dressed couple of the night, Pitt (in Tom Ford) and Jolie (in Atelier Versace) glided down the red carpet at the 68th Annual Golden Globe Awards. Jolie was nominated for Best Performance in a Motion Picture — Musical or Comedy, but lost to The Kids Are All Right's Annette Bening.
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