Costar Couples

Brad Pitt and Angelina Jolie

Though he was married to Jennifer Aniston at the time, Pitt couldn't take his eyes off of Jolie on the set of Mr. & Mrs. Smith in 2004. "I think we were the last two people who were looking for a relationship," Jolie later told Vogue. It wasn't until shooting nearly ended that Pitt and Jolie realized "it might mean something more than we'd earlier allowed ourselves to believe."

ADVERTISEMENT

Inside Us Weekly

comments powered by Disqus