Paul Wesley and Torrey DeVitto/Phoebe Tonkin
Wesley and DeVitto first met during filming of the Killer Movie in 2008, but announced they were getting divorced after two years of marriage in June 2013. The CW star didn't stay single for long, eventually romancing Vampire Diaries costar Phoebe Tonkin in September 2013. (DeVitto has also appeared on the series.) "Paul and Phoebe were 100% romantic," an eyewitness told Us exclusively of a date the pair had in September 2013. "She had her head on his chest."