Zooey Deschanel and Piper Perabo aside, Hollywood's biggest celebs dressed their best at the 69th Annual Golden Globe Awards in Beverly Hills, Calif. Sunday.

Angelina Jolie, 36, looked regal in an Atelier Versace gown as she sauntered down the red carpet with partner Brad Pitt, 48, who wore a Ferragamo tuxedo.

Last year's big winner Natalie Portman made her red carpet return in a custom-made dress by Lanvin. The 30-year-old Black Swan star and new mom was joined by her fiance, French choreographer Benjamin Millepied, 34.

Jolie and Portman weren't the only A-list beauties who made strong style statements: Reese Witherspoon unveiled a vampy new look in Zac Posen, Charlize Theron channeled old Hollywood glamour in Dior and Jessica Biel looked downright bridal in Elie Saab.

To see which other stars walked the red carpet -- including Madonna, Kate Winslet, Michelle Williams, Salma Hayek, Nicole Kidman, and more -- watch the video (above) now!