Rachel Bilson's back!

Starting September 26, the former O.C. starlet beloved by fans will appear as spunky doc Zoe Hart on The CW's Hart of Dixie.

From the creators of Gossip Girl, Bilson's new series -- costarring Jamie King and Scott Porter -- finds the 29-year-old actress transplanted from New York City to Bluebell, Ala., forced to maintain a small medical practice on her own.

The fish-out-of-water dramedy will reunite Bilson with her O.C. executive producer, Josh Schwartz, who also acts as EP on Hart of Dixie. "I knew if I came back to TV it would have to be with Josh, so I'm really excited I get to torture him again," Bilson joked to Us Weekly in May about her small screen return.

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Check out a sneak peek of Hart of Dixie above and tell Us: Will you tune in to Rachel Bilson's return to TV?