Blake Shelton and Miranda Lambert's Love Story

CMT 100 Greatest Duets Concert

The duo first met back in 2005 at CMT's 100 Greatest Duets Concert, where they performed together. "I didn't know if it was just initial butterflies… I don't know what it was," Lambert said of first meeting him. Shelton, backing up her claim, told VH1: "Looking back on that, I was falling in love with her, right there on stage."

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