Gossip Girl's Chace Crawford, Katy Perry and Ne-Yo are set to present at the MTV Video Music Awards Sept. 13 in New York City, Usmagazine.com can exclusively reveal.

Check out the most talked-about moments from the 2008 VMAs!

Perry and Crawford both participated in last year's broadcast, held at Hollywood's Paramount Studios. Perry performed her summer smash "I Kissed a Girl," while the actor presented the Moonman trophy for Best New Artist, along with Lauren Conrad, to rockers Tokio Hotel.

See last year's best dressed stars.

Crawford, Perry and Ne-Yo join previously announced talent Taylor Swift, who will perform a never-before-heard version of "You Belong With Me," and Russell Brand, who is hosting the show for the second year in a row.

MTV will air the 2009 Video Music Awards live from Radio City Music Hall on Sept. 13.

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