The Oscar-winning actress, 39, is gorgeous on the simple cover shot by Mario Testino, staring straight into the camera for a captivating shot. With the focus on her piercing blue eyes, Jolie wears her brunette locks pulled back away from her face, and sports a classic nude lip.
Jolie poses in a white collared shirt with her arms wrapped around herself, offering a peek at her massive engagement ring. The image of the star is accompanied by cover lines reading "Perfectly Awesome! Angelina Jolie: Visiting War Zones, Directing an Oscar Contender, and Life as Mrs. Pitt."
Inside the issue, the mother of six touched on her life in the months since her secret August wedding to longtime love Brad Pitt.
"It does feel different," she told the mag about being a married couple after nine years together. "It feels nice to be husband and wife."
Jolie and Pitt, 50, were wed in a surprise ceremony in France, exchanging vows in front of their friends and family, including children Maddox, 13, Pax, 10, Zahara, 9, Shiloh, 8, and twins Knox and Vivienne, 6.
The By the Sea actress explained to Vanity Fair that her expansive brood also took part in her wedding vows to Pitt.
"They did not expect us never to fight, but they made us promise to always say, 'Sorry,' if we do," she spilled. "So they said, 'Do you?,' and we said, 'We do!'"
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