Credit: Brendan Smialowski/Getty Images

Hollywood's most powerful couple came face-to-face with the most powerful man in the United States Wednesday.

Angelina Jolie, 36, and Brad Pitt, 48, were escorted inside the White House by several security guards, where they met with President Barack Obama, 50, inside the Oval Office. The actors first arrived in Washington, DC Tuesday for the premiere of Jolie's directorial debut, In the Land of Blood and Honey. See more pics of Brad and Angie at the White House from PopSugar.

According to the Associated Press, the actors "dropped by so [President Obama] could talk with Jolie about her work on preventing mass atrocities and combating sexual violence against women."

Pitt -- who has been a longtime supporter of Obama -- first met the politician in 2009 to discuss his work rebuilding New Orleans' 9th Ward after Hurricane Katrina.