Rihanna
The Video of the Year winner — debuting a newly cropped hairstyle — wore a custom Adam Selman dress, Neil Lane earrings and Jacqui Aiche rings.
2012 MTV Video Music Awards: What The Stars Wore
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Pink
Willow's mama looked fierce in a metallic Stella McCartney frock, with jewelry by Loree Rodkin.
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Taylor Swift
The "Mean" crooner looked sleek in a J. Mendel suit and top, Tom Ford shoes and Lorraine Schwartz jewels.
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Nicki Minaj
The sartorial standout donned a bright yellow wig and sheer, bejeweled Versace jumpsuit for her big night -- she took home the "Best Female Video" Moonman!
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Katy Perry
Eat your heart out, Russell Brand! The "Part of Me" singer stunned in a teal and fuschia sequin embroidered Elie Saab gown.
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Emma Watson
Hermione who? The Perks of Being a Wallflower star looked ultra-glam in a graphic, printed mini-dress.
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Rashida Jones
The Celeste and Jesse Forever actress stunned in a low-cut black leather dress and Neil Lane Jewelry.
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Demi Lovato
A little bit rock-and-roll! The X Factor judge added some edge to a flirty, sparkly black frock by accessorizing her look with a studded leather bomber jacket.
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Miley Cyrus
The freshly shorn future Mrs. Hemsworth looked edgy in a black silk organza Emilio Pucci gown and an Edie Parker clutch.
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Alicia Keys
The R&B singer glowed in a curve-hugging Alexandre Vauthier gown, strappy Gucci shoes and Loree Rodkin jewels.
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Ke$ha
The "Die Young" singer wore a Zaldy dress, Prada shoes, a Marie Todd ring and Karma El Khalil rings and earrings.
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Kat Graham
The Vampire Diaries actress stunned in a satin maroon pantsuit, leopard print bustier and Ruthie Davis pumps.
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Rita Ora
The British songstress rocked an Emilio Pucci jumpsuit, Sergio Rossi pumps, and carried a Jimmy Choo clutch.
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Zoe Saldana
The Words star showed off her stems in a Salvatore Ferragamo frock and shoes; she accessorized with an Alexander McQueen clutch.
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One Direction
The adorable British boy banders walked the red carpet just a few minutes before snagging their first Moonman ever -- thanks to their "Most Share-Worthy Video" Award.
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Jessica Szohr
The Gossip Girl stunner showed off her slim frame in a black bustier and flowing maxi skirt.
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Jackson Rathbone
The Twilight star looked dapper in an all-black get-up during his red carpet walk.
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Wiz Khalifa and Amber Rose
With her fiance by her side, the proud mama-to-be showed off her burgeoning baby bump in a formfitting nude gown boasting black floral appliques. (She accessorized with Neil Lane jewelry.)
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The Wanted
The U.K.-bred rockers struck a pose before taking their seats inside L.A.'s Staples Center.
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The Fierce Five
Team USA's McKayla Maroney, Jordyn Wieber, Kyla Ross, Gabby Douglas and Aly Raisman posed like pros.
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Maria Menounos
The Extra correspondent looked sexy in short black leather dress.
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Colton Haynes
The hunky Teen Wolf actor looked handsome in a gray Hugo Boss suit and bright blue dress shirt.
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Crystal Reed
The Teen Wolf beauty wore an Alexander McQueen dress.
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Kreayshawn
The hip-hop star wore head-to-toe black.
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Tyler Posey
The Teen Wolf lead sported a Boss Black suit and Boss Orange shirt.
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Missy Franklin
The Olympic gold medalist wore a bright halter dress and stripy sandals.
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Holland Roden
The Teen Wolf actress sparkled in a Pamella Roland dress.
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Sammi "Sweeatheart" Giancola
The Jersey Shore star looked sassy in a black and gold mini-dress.
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Deena Nicole Cortese
The MTV reality star squeezed into an embellished black mini-dress and gold platform heels.
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