Thirty minutes before the Golden Globes began, Brad Pitt and Angelina Jolie arrived on the red carpet Sunday. She was spotted fixing Pitt's bow tie as they stepped on to the carpet.

See what Angelina Jolie and all the stars wore to the 2009 Golden Globe Awards!

Jolie - who dodged E!'s Ryan Seacrest when he tried to approach her for an interview with Pitt - wore an Atelier Versace gown, Platinum by Neil Lane jewelery and Jimmy Choo shoes.

See how Angelina Jolie's red carpet style has changed over the years.

Pitt is nominated for his leading dramatic role in The Curious Case of Benjamin Button, while Jolie is up for her leading dramatic role in Changeling.

Look at Brad Pitt and Angelina Jolie's family photo album.