Ben Gibbard and Zooey Deschanel
The pair got engaged in December 2008 and tied the knot in September 2009 near Seattle, Washington. However, after just two years, the New Girl star filed for divorce from the Death Cab for Cutie frontman. "I'd seen her movies and obviously I thought she was very beautiful," Gibbard previously told New York Magazine. He added, "I was just awestruck that she was even talking to me."