There's no doubt about it: Freddie Prinze, Jr. has that It factor to make women swoon, and lucky for Witches of East End's Wendy (Madchen Amick), her chemistry with Prinze's character Leo is magic in more ways than one. In a sneak peek from the Sunday, Oct. 27 episode of Lifetime's supernatural drama, the alluring Wendy is drawn to Leo after meeting him unexpectedly in the halls of his apartment building.

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Over a glass of red wine, Leo and Wendy chat about Leo's career as Wendy tries to secure a new ingredient for her latest protection spell. Initially hesitant to get close to Leo, she attempts to slip out of his apartment unnoticed when he goes to change his shirt and clean up a wine stain, only to find him shirtless and oozing sex appeal when he returns.

"I can stay for a few more minutes," says Wendy, clad in just an oversize button-down, rushing over to make out with him. "I'm not very good at goodbyes. I'm much better at hellos!"

Married in real life to Sarah Michelle Gellar, Witches of East End guest star Prinze -- the father of Charlotte, 4, and Rocky, 13 months -- is returning to TV after years as a stay-at-home dad. His wife was able to go back to work and currently appears on CBS' The Crazy Ones. "He's like, 'You stayed home for two years! It's my turn!" Gellar told Us.

Witches of East End airs Sundays at 10 p.m. (EST) on Lifetime.