See which A-list twosomes sparked a romance as cameras rolled
Brad Pitt and Angelina Jolie
"Because of the film, we ended up [doing] all these crazy things, and...found this strange friendship and partnership that kind of just suddenly happened," Jolie has said of meeting Pitt during Mr. & Mrs. Smith's filming. "I think a few months in I realized, 'God, I can't wait to get to work."
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