From Mr. and Mrs. Smith to Mr. and Mrs. Pitt! Brad Pitt and Angelina Jolie have had quite the journey from costars, to parents, to spouses. The A-list couple had a scandalous start to their romance when they met on the set of Mr. & Mrs. Smith, while Pitt was still married to Jennifer Aniston. But the couple, who are parents to six kids, has built a long-lasting relationship. Click through to see their romantic history.
Sparks flew on the set of Mr. & Mrs. Smith (released the following year), despite the fact that Pitt was married to Jennifer Aniston at the time. "I think we were the last two people who were looking for a relationship. I certainly wasn't," Jolie later told Vogue. "We found this strange friendship and partnership that kind of just suddenly happened. I think a few months in I realized, 'God, I can't wait to get to work.'"
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