Who wore it best? Not Angelina Jolie.
The mom of six dropped off Vanity Fair's best dressed list this year.
See Angelina Jolie's hottest red carpet photos
Brad Pitt was named for the third year in a row -- although in 2007 and 2008, he appeared in the "couples category" with Jolie.
See Brad and Angie's most romantic moments
President Barack Obama was named to the list for the first time. The First Lady, Michelle Obama, appears for the third time.
Check out Michelle Obama's most chic looks
Penelope Cruz, Anne Hathaway, Alicia Keys, and Kelly Ripa are ranked for the first time. The September issue of Vanity Fair hits newsstands on Aug. 11.