Credit: Michael Caulfield/; Nicole Rivelli/NBC

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Former secretary of state Condoleezza Rice will make a guest appearance on 30 Rock this season, reports

Rice, 56, will be playing an ex-girlfriend of Alec Baldwin's character, network executive Jack Donaghy, Tina Fey told reporters Thursday.

During the NBC hit's first season, Donaghy claimed he had dated a "high-ranking African-American member of the Bush Administration," but said he split with his "neocon inamorata" because they weren't compatible.

This won't be the first time Fey, 40, has worked with a GOP star. She famously spoofed Sarah Palin on Saturday Night Live during the 2008 presidential election, and riffed alongside the former Alaska Governor when Palin guest starred on the show.

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Still, when asked if she would consider running for office herself, Fey scoffed, "No way, that's for suckers."

There is one cause, the Bossypants author does get riled up about -- making sure her Emmy-winning costar, 53, keeps people laughing.

Says Fey, "I would lobby Capitol Hill for a law to require Alec Baldwin to stay in show business."