Watch Angelina Jolie and Brad Pitt’s Best Red Carpet Moments

It’s been over 24 hours since the Brangelina news broke, and it’s still tearing Us up! Angelina Jolie and Brad Pitt, who confirmed their divorce on Tuesday, September 20, were undeniably one of the most iconic couples to walk the red carpet. Relive their happier (and stylish!) times in today’s Red Carpet Daily, presented by AT&T.

Getty Images

Let’s start from the beginning: their red carpet debut in December 2006. Although they'd already been together since 2004 and had welcomed daughter Shiloh that May, Jolie, now 41, and Pitt, now 52, marked their first-ever red carpet appearance at the premiere of The Good Shepherd in New York City. Jolie, who shares Maddox, 15, Pax, 12, Zahara, 11, Shiloh, 10, and twins Knox and Vivienne, 8, with her ex, glowed in a sparkly wrap dress.

Getty Images

By the time the 2012 Oscars rolled around, the duo were old pros at these kinds of things. Jolie set social media atwitter by poking her long, lean leg out of her strapless black Atelier Versace gown. All Pitt could do was smile, as he looked dapper in his flawlessly tailored tux.

Keep watching Red Carpet Daily for more of our favorite Brangelina moments. Plus, get the scoop on one of fall 2016’s top trends — the denim skirt, as modeled by Reese Witherspoon, Karlie Kloss  and more.

(Wardrobe: Topshop and Fashion Junkee)

Sign up now for the Us Weekly newsletter to get breaking celebrity news, hot pics and more delivered straight to your inbox!

Want stories like these delivered straight to your phone? Download the Us Weekly iPhone app now!