See Who Made Us' List of Stars Who Care

Angelina Jolie & Brad Pitt

Inspired by their kids to give back, the couple donated $6.4 million to charities in 2008 alone. While U.N. goodwill ambassador Jolie focuses her efforts in third-world countries, her partner pitches in closer to home, rebuilding more than 50 Hurricane Katrina-ravaged houses in New Orleans.

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