David Beckham, Selma Blair, Whoopi Goldberg and More!
When Katy Perry first met Russell Brand after he hosted the MTV VMAs in September 2009, he had no idea what hit him -- literally! "I was 25, 30 feet away from him. And I threw the bottle straight at him -- hit him smack dab on the head," she later told Esquire. "I was like, 'You've met your match.'"