Credit: Larry Busacca/Getty Images; Paul Morigi/

Jessica Biel and Bradley Cooper teamed up on-screen last February for the ensemble flick Valentine's Day, and now the pair are set to work together again at MTV's 2010 Movie Awards, has confirmed.

Biel, 28, and Cooper, 35 will take the stage with fellow presenters Shaun White, Jonah Hill, Steve Carell and Russell Brand to hand out golden popcorn trophies at the June 6 ceremony. This year, MTV will honor the year's top flicks in categories including Best Kiss, Best Fight and Best WTF Moment.

Parks and Recreation star Aziz Ansari will host the annual event, airing live from the Gibson Amphitheater in Universal City, Calif.

Online voting for this year's categories begins May 11.